Issue 7, 1978

Complexes of pyrimidine-2-thione with some bivalent metal halides of the first transition series

Abstract

The preparations are reported of complexes of pyrimidine-2-thione (Hpymt) with halides of MnII, FeII, CoII, NiII, ZnII and CdII. The complexes have stoicheiometry ML2X2. A combination of X-ray, electronic spectral, i.r., e.s.r:, and, for iron, Mössbauer studies shows that, in most cases, the sulphur atom, as well as the non-protonated ring nitrogen atom, of the thione ligand co-ordinates to the metal to give a four-membered chelate ring. Some inner complexes [M(pymt)2](M = Co, Ni, or Zn) are also reported.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1978, 880-884

Complexes of pyrimidine-2-thione with some bivalent metal halides of the first transition series

J. Abbot, D. M. L. Goodgame and I. Jeeves, J. Chem. Soc., Dalton Trans., 1978, 880 DOI: 10.1039/DT9780000880

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements