Thermodynamics of metal complex formation in aqueous melts of calcium dinitrate–ammonium nitrate. Part 2. Cadmium(II) bromides
Abstract
The formation constants of [CdBr]+ and CdBr2 in melts of Ca[NO3]2·a[NH4][NO3]·xH2O (a= 1.5—1 1.5,x= 0—8), in the range 323–433 K, have been determined from e.m.f. measurements in suitable concentration cells. The results are discussed in terms of a previously developed model based on the quasi-lattice concept of aqueous melts.