A physical derivation of the rigorous theory for chemical equilibria and intramolecular structures of non-rigid molecules in condensed phases is presented. Applications of the theory are reviewed and the importance of steric or packing effects on equilibrium chemical phenomena in liquids is stressed.
D. Chandler, Faraday Discuss. Chem. Soc., 1978, 66, 184 DOI: 10.1039/DC9786600184
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