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Issue 3, 1978
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Proposal for the mechanism of inversion of alkyl-lithiums

Abstract

The experimentally observed inversion at the RCH2Li carbon within alkyl-lithium aggregates is indicated by ab initio molecular orbital calculations on model compounds to involve novel RCH2Li2 fragments in which two lithium atoms stabilize a planar RCH2 group.

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Article information


J. Chem. Soc., Chem. Commun., 1978, 137-138
Article type
Paper

Proposal for the mechanism of inversion of alkyl-lithiums

T. Clark, P. v. R. Schleyer and J. A. Pople, J. Chem. Soc., Chem. Commun., 1978, 137
DOI: 10.1039/C39780000137

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