SCHEDULED MAINTENANCE
Perfluorotetramethylfuran (7) is obtained in a cyclisation reaction of the perfluoro-olefin (1) using triethylamine and methanol, the process involving a novel defluorination; a cyclisation is described which clearly involves the rare displacement of fluoride ion from a saturated position in a perfluoroalkyl group.
R. D. Chambers, A. A. Lindley, P. D. Philpot, H. C. Fielding, J. Hutchinson and G. Whittaker, J. Chem. Soc., Chem. Commun., 1978, 431b DOI: 10.1039/C3978000431B
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