Geissoschizine (10) is not a central intermediate in the biosynthesis of ajmalicine (7) and the related Corynanthe alkaloids (8) and (9), but rather enters the main pathway by a NADP+ dependent reaction.
J. Stöckigt, J. Chem. Soc., Chem. Commun., 1978, 1097 DOI: 10.1039/C39780001097
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