Primary allylic sulphides of benzothiazole-2-thiol react with butylmagnesium bromide in the presence of copper(I) iodide to yield, depending on the solvent, olefins with or without allylic rearrangement.
P. Barsanti, V. Calò, L. Lopez, G. Marchese, F. Naso and G. Pesce, J. Chem. Soc., Chem. Commun., 1978, 1085 DOI: 10.1039/C39780001085
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