The deaminase–cosynthetase enzyme system ring closes the unrearranged bilane (2) far more efficiently than it closes any of five synthesised isomeric bilanes, thus supporting (2) as the key intermediate of type-III porphyrin biosynthesis.
A. R. Battersby, C. J. R. Fookes, G. W. J. Matcham and E. McDonald, J. Chem. Soc., Chem. Commun., 1978, 1064 DOI: 10.1039/C39780001064
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