Platinum(IV) complexes with π-acceptor ligands
Abstract
Complexes of the type [NBun4][PtX5(PY3)](X = Cl or Br; Y = F, Cl, Br, or OMe) have been prepared, and the anions[PtX5(CO)]– identified in solution; the relationship between Pt–donor atom n.m.r. couplings of these and corresponding PtII complexes is discussed.