Issue 23, 1978

Lithium phenylthio(trimethylstannyl)cuprate, a new reagent for conjugate addition of the Me3Sn group. The synthesis of β-trimethylstannyl-αβ-unsaturated ketones

Abstract

Treatment of a solution of Me3SnLi in tetrahydrofuran with 1 equiv. of PhSCu affords PhS(Me3Sn)CuLi, a new reagent which efficiently transforms β-iodoenones into β-trimethylstannyl-αβ-unsaturated ketones, a new class of organotin derivatives.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 1033-1034

Lithium phenylthio(trimethylstannyl)cuprate, a new reagent for conjugate addition of the Me3Sn group. The synthesis of β-trimethylstannyl-αβ-unsaturated ketones

E. Piers and H. E. Morton, J. Chem. Soc., Chem. Commun., 1978, 1033 DOI: 10.1039/C39780001033

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