Reaction of RhIII porphyrins with diazoalkanes leads to the formation of metal-alkylated products; significant differences from the corresponding CoIII series are noted, e.g., catalytic decomposition of the reagents and fragmentation of primary olefinic products to give Rh(CO2R) porphyrins.
H. J. Callot and E. Schaeffer, J. Chem. Soc., Chem. Commun., 1978, 937 DOI: 10.1039/C39780000937
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