Issue 21, 1978

An easy vinylcyclobutane–cyclohexane rearrangement

Abstract

1-(2,2-Dicyclopropylvinyl)-2,2,3,3-tetracyanocyclobutane (2a), which was obtained in the reaction of 1,1-dicyclopropylbuta-1,3-diene (1a) with tetracyanoethylene, rearranged smoothly to the cyclohexene (3a) in a polar solvent, whereas 1-(2,2-di-isopropylvinyl)-2,2,3,3-tetracyanocyclobutane (3d) fragmented into methylene-malononitrile and the diene (4).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 931-932

An easy vinylcyclobutane–cyclohexane rearrangement

N. Shimizu and S. Nishida, J. Chem. Soc., Chem. Commun., 1978, 931 DOI: 10.1039/C39780000931

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