X-Ray analysis has shown the presence of two structural isomers of the [H3Ru4(CO)12]– anion with metal–hydrogen geometries approximating to C2 and C3v symmetry; although the presence of structural isomers has been postulated for several metal carbonyl hydrides, this work presents the first confirmation of their existence in the solid state.
P. F. Jackson, B. F. G. Johnson, J. Lewis, M. McPartilin and W. J. H. Nelson, J. Chem. Soc., Chem. Commun., 1978, 920 DOI: 10.1039/C39780000920
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