Issue 21, 1978

Syntheses and reactivity of cofacial, dimeric metal–metal bonded ruthenium(II) mixed valence ruthenium(II/III), and ruthenium(III) complexes of [C22H22N4]2–, a dibenzo-tetra-aza[14]annulene ligand

Abstract

A novel series of metal–metal bonded RuII, mixed valence RuII/III, and RuIII complexes [Ru(C22H22N4)]2n+, of a dibenzotetra-aza[14]annulene ligand have been isolated and characterized which possess ground spin-triplet, spin-doublet, and singlet states, respectively.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 909-910

Syntheses and reactivity of cofacial, dimeric metal–metal bonded ruthenium(II) mixed valence ruthenium(II/III), and ruthenium(III) complexes of [C22H22N4]2–, a dibenzo-tetra-aza[14]annulene ligand

L. F. Warren and V. L. Goedken, J. Chem. Soc., Chem. Commun., 1978, 909 DOI: 10.1039/C39780000909

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