Issue 20, 1978
From the journal:

Journal of the Chemical Society, Chemical Communications

Sulphur inversion in dimolybdenum complexes: X-ray crystal structure of [Mo2(CO)2{P(OMe)3}(µ2-SBut)3(η7-C7H7)]

Ian B. Benson,   Selby A. R. Knox,   Pamela J. Naish  and  Alan J. Welch  

Abstract

Low energy barriers are observed for sulphur inversion in complexes [Mo2(CO)2(L)(µ2-SR)3(η7-C7H7)](R = Me, Et, Pri, or But); n.m.r. spectroscopy reveals complete averaging of R group environments when L = CO but only a limited averaging when L = PR′3, a situation clarified by an X-ray diffraction study of [Mo2(CO)2{P(OMe)3}(µ2-SBut)3(η7-C7H7)].

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Article information

DOI
https://doi.org/10.1039/C39780000878
Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 878-879

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Sulphur inversion in dimolybdenum complexes: X-ray crystal structure of [Mo2(CO)2{P(OMe)3}(µ2-SBut)3(η7-C7H7)]

I. B. Benson, S. A. R. Knox, P. J. Naish and A. J. Welch, J. Chem. Soc., Chem. Commun., 1978, 878 DOI: 10.1039/C39780000878

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