Calorimetric studies show that the 14-membered macrocycle (1) incorporates copper(II) more exothermically than its less symmetric isomer (2), owing to stronger in-plane Cu–N interactions; introduction of a pyridine ring in the macrocyclic framework (3) further reduces the heat of complexation.
L. Fabbrizzi, M. Micheloni and P. Paoletti, J. Chem. Soc., Chem. Commun., 1978, 833 DOI: 10.1039/C39780000833
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...