Formation of a novel complex between pyridinium bis(alkoxycarbonyl)methylides and diphenylcyclopropenone; trapping of pyridinium bis(alkoxycarbonyl)methylide cation radicals
Abstract
Reactions of pyridinium bis(alkoxycarbonyl)methylides with diphenylcyclopropenone in refluxing acetonitrile produce the corresponding 1 : 1 complexes (3), e.s.r. analysis of which indicates the presence of radical cations of the ylides (1).
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