Ethylchloro-, isopropylchloro-, and t-butylchloro-carbenes have been generated by photolysis of the corresponding 3-alkyl-3-chlorodiazirines and added to several alkenes; the partition between intermolecular interception and intramolecular liquidation of the carbenes was mainly dependent on the structure of the carbenic alkyl groups.
R. A. Moss and R. C. Munjal, J. Chem. Soc., Chem. Commun., 1978, 775 DOI: 10.1039/C39780000775
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