Gentisic acid, accumulated from 4-hydroxybenzoic acid by bipyridyl-inhibited cells of Bacillus stearothermophilus, is formed by hydroxylation effecting intramolecular ortho migration of a carboxy-group with no observed exchange with hydrogen carbonate.
S. L. Keenan and P. J. Chapman, J. Chem. Soc., Chem. Commun., 1978, 731 DOI: 10.1039/C39780000731
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