Issue 16, 1978
From the journal:

Journal of the Chemical Society, Chemical Communications

Isomerisation of allyl ethers catalysed by the cationic iridium complex [Ir(cyclo-octa-1,5-diene)(PMePh2)2]PF6. A highly stereoselective route to trans-propenyl ethers

Denise Baudry,   Michel Ephritikhine  and  Hugh Felkin  

Abstract

Allyl alkyl (and aryl) ethers are isomerised by H2-activated [Ir(cyclo-octa-1,5-diene)(PMePh2)2]PF6 in tetrahydrofuran or dioxan at room temperature to the corresponding trans-propenyl ethers (yields [gt-or-equal] 95%; stereoselectivity [gt-or-equal] 97%).

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Article information

DOI
https://doi.org/10.1039/C39780000694
Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 694-695

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Isomerisation of allyl ethers catalysed by the cationic iridium complex [Ir(cyclo-octa-1,5-diene)(PMePh2)2]PF6. A highly stereoselective route to trans-propenyl ethers

D. Baudry, M. Ephritikhine and H. Felkin, J. Chem. Soc., Chem. Commun., 1978, 694 DOI: 10.1039/C39780000694

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