SCHEDULED MAINTENANCE
The thermal rearrangements of the ammonium ylides (1) give products formally derived from competing [1,2], [1,3], and [1,4] rearrangements; the intramolecularities of these processes are compatible with a radical pair mechanism involving initial homolysis of the ylide (1) followed by three possible modes of radical pair recombination (Scheme).
K. Chantrapromma, W. D. Ollis and I. O. Sutherland, J. Chem. Soc., Chem. Commun., 1978, 670 DOI: 10.1039/C39780000670
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