In the structure of [La(NO3)3(H2O)5]·H2O (determined by X-ray crystallography) the lanthanum atom is surrounded by three bidentate nitrate ligands and five water molecules; this result indicates a hitherto unknown co-ordination number of eleven for a trivalent lanthanoid.
B. Eriksson, L. O. Larsson and L. Niinistö, J. Chem. Soc., Chem. Commun., 1978, 616 DOI: 10.1039/C39780000616
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