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Issue 14, 1978
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Co-ordination chemistry of macrocyclic polyethers. An unusual conformation of complexed 18-crown-6; X-ray crystal and molecular structure of a 1:2 host–guest complex of 18-crown-6 with benzenesulphonamide

Abstract

In the 1:2 host–guest complex formed between 1,4,7,10,13,16-hexaoxacyclo-octadecane (18-crown-6) and benzenesulphonamide, the crown ether adopts nearly the same conformation as the uncomplexed hexaether; the complex is held together mainly by N–H ⋯ O hydrogen bonds.

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Article type: Paper
DOI: 10.1039/C39780000595
Citation: J. Chem. Soc., Chem. Commun., 1978,0, 595-596
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    Co-ordination chemistry of macrocyclic polyethers. An unusual conformation of complexed 18-crown-6; X-ray crystal and molecular structure of a 1:2 host–guest complex of 18-crown-6 with benzenesulphonamide

    A. Knöchel, J. Kopf, J. Oehler and G. Rudolph, J. Chem. Soc., Chem. Commun., 1978, 0, 595
    DOI: 10.1039/C39780000595

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