Anaerobic photolysis of adenosyl- and methyl-cobalamins in an aqueous KCl–HCl buffer (pH 2·0) in the presence of SH-compounds (e.g. dihydrolipoic acid amide) causes conversion of ethylene glycol into acetaldehyde, and provides a model for the dioldehydratase enzymic reaction.
I. P. Rudakova, T. E. Ershova, A. B. Belikov and A. M. Yurkevich, J. Chem. Soc., Chem. Commun., 1978, 592 DOI: 10.1039/C39780000592
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