Issue 13, 1978

An electron spin resonance study of the cyclobutylhydroxymethyl radical: its conformation, and its ring opening followed by 1,6-transfer of enolic hydrogen

Abstract

The e.s.r. spectra show that in fluid solution the cyclobutylhydroxymethyl radical adopts a staggered conformation like that of cyclopropylmethyl radicals; in adamantane, cyclobutylhydroxymethyl radicals undergo ring-opening followed by 1,6-transfer of enolic hydrogen to give penten-1-oxyl radicals.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 569-571

An electron spin resonance study of the cyclobutylhydroxymethyl radical: its conformation, and its ring opening followed by 1,6-transfer of enolic hydrogen

P. M. Blum, A. G. Davies and R. A. Henderson, J. Chem. Soc., Chem. Commun., 1978, 569 DOI: 10.1039/C39780000569

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