Reaction of [MeN(PF2)2]3Co2(CO)2 with Br2 in diethyl ether gives red-brown [MeN(PF2)2]3Co2Br4 shown by single crystal X-ray diffraction to retain the [MeN(PF2)2]3Co2 unit consisting of a cobalt–cobalt bond bridged by three MeN(PF2)2 ligands.
M. G. Newton, N. S. Pantaleo, R. B. King and T. J. Lotz, J. Chem. Soc., Chem. Commun., 1978, 514 DOI: 10.1039/C39780000514
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