Through pyrolysis of 7,7-dideuterio-anti-1,5-bishomocycloheptatriene, evidence has been obtained that thermal rearrangement of this ring system proceeds by twofold 1,5-homodienyl rearrangement, the second stage of which involves prior conformational ring inversion and geminal hydrogen interchange.
M. R. Detty and L. A. Pquette, J. Chem. Soc., Chem. Commun., 1978, 365 DOI: 10.1039/C39780000365
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