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The 13C-labelling patterns in β-sitosterol, isolated from Isodon japonicus Hara tissue cultures fed with [4-13C]mevalonic acid and [1,2-13C]acetate, provide confirmatory evidence for the postulated backbone rearrangement during biosynthesis of β-sitosterol, and also suggest that biological alkylation at C-24 is stereospecific.
S. Seo, Y. Tomita and K. Tori, J. Chem. Soc., Chem. Commun., 1978, 319 DOI: 10.1039/C39780000319
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