Conversion electron Mössbauer spectroscopy shows that iron(II) phosphate octahydrate is formed as a surface phase when metallic iron is treated by two different phosphating processes; modest heating in air dehydrates this surface species to iron(II) phosphate tetrahydrate whereas the bulk octahydrate is converted under similar conditions into an iron(III) species.
F. J. Berry and A. G. Maddock, J. Chem. Soc., Chem. Commun., 1978, 308 DOI: 10.1039/C39780000308
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