Issue 7, 1978

Spin trapping experiments on nadh analogues and the role of radicals in carbonyl reductions

Abstract

1 H N.m.r. and gas chromatographic analysis of the reactants and products show that the reaction of N-benzyl-1,4-dihydronicotinamide (NBDN), an analogue of NADH, with pyridine-2-carbaldehyde does not pass through a radical intermediate during either a thermal or a photolytic reaction; photolysis led to the removal of NBDN but not to the production of the reduced substrate and radicals detected with e.s.r. spectroscopy were shown to be artifacts.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 300-301

Spin trapping experiments on nadh analogues and the role of radicals in carbonyl reductions

R. A. Hood, Reg. H. Prince and K. A. Rubinson, J. Chem. Soc., Chem. Commun., 1978, 300 DOI: 10.1039/C39780000300

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