In the reaction of (η3-vinylcarbene)Fe(CO)3 with triphenylphosphine or carbon monoxide (L), the η3-vinylcarbene ligand was carbonylated affording an apparent ‘η4-vinylketen complex,’ which was shown by X-ray analysis to have the alternative (η3-allyl +η1-acyl)FeII(CO)2L structure.
T. Mitsudo, T. Sasaki, Y. Watanabe, Y. Takegami, S. Nishigaki and K. Nakatsu, J. Chem. Soc., Chem. Commun., 1978, 252 DOI: 10.1039/C39780000252
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