Methyl 7-trimethylsilylbicyclo[2.2.1]hept-5-ene-2-carboxylate (3) and its epoxide (8) rearrange on treatment with bromine or boron trifluride, respectively, to give 7-functionalised norbornenes (6) or (7).
I. Fleming and J. P. Michael, J. Chem. Soc., Chem. Commun., 1978, 245 DOI: 10.1039/C39780000245
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