Both the labile gem-dialkylthio-adduct (2) of attack of methanethiolate at C(2) of 2-methylthio-5-nitrotropone and its spiro analogue (1), which is in equilibrium with the prevailing non-cyclized form, have been obtained; the absence of the 5-nitro-group leads either to non-gem-adducts or to no adduct at all.
M. Cavazza, C. A. Veracini, G. Morganti and F. Pietra, J. Chem. Soc., Chem. Commun., 1978, 167 DOI: 10.1039/C39780000167
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