Ab initio MO calculations on the title compounds are in good agreement with the recently published photo-electron spectra but not with the corresponding proposed MO scheme; the calculations show the first PE band to be mainly, phosphorous in character rather than oxygen.
L. W. Yarbrough and M. B. Hall, J. Chem. Soc., Chem. Commun., 1978, 161 DOI: 10.1039/C39780000161
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