Chlorine monofluoride oxidatively chlorofluorinates tetrafluoro-1,3-dithietan to form the first example of a stable fluorine-containing dichlorosulphur compound, [graphic omitted]F2; with LiN![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
C(CF3)2 and CH3N[Si(CH3)3]2, the first examples of fluorinated pentaco-ordinate dichlorosulphimides, [(CF3)2CFN][graphic omitted]F2 and (CH3N)[graphic omitted]F2 are obtained.
T. Kitazume and J. M. Shreeve, J. Chem. Soc., Chem. Commun., 1978, 154 DOI: 10.1039/C39780000154
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