Of the two alternative structures we previously derived for sirohydrochlorin, the preferred one (3) is now established by specific incorporation of methyl-labelled sirohydrochlorin into cobyrinic acid (6) followed by degradation to determine the labelling pattern.
A. R. Battersby, E. McDonald, M. Thompson and V. Ya. Bykhovsky, J. Chem. Soc., Chem. Commun., 1978, 150 DOI: 10.1039/C39780000150
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