Irradiation of the enol acetates derived from several substituted 4-(prop-2-enyl)cyclopentane-1,3-diones leads to photoproducts resulting from intramolecular [2 + 2] cycloaddition, which can then be elaborated to the bicyclo[3.2.1]octane ring system.
M. Mellor, D. A. Otieno and G. Pattenden, J. Chem. Soc., Chem. Commun., 1978, 138 DOI: 10.1039/C39780000138
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