15  N nuclear magnetic resonance studies of iron(II) low spin complexes of 15N and 57Fe labelled porphyrin

Isao Morishima; Toshiro Inubushi; Mitsuo Sato

doi:10.1039/C39780000106

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¹⁵N nuclear magnetic resonance studies of iron(II) low spin complexes of ¹⁵N and ⁵⁷Fe labelled porphyrin

Isao Morishima, Toshiro Inubushi and Mitsuo Sato

Abstract

¹⁵ N n.m.r. chemical shifts and ¹J(¹⁵N–⁵⁷Fe) coupling constants have been obtained for Fe^II low spin bis(amnine) complexes of [¹⁵N₄, ⁵⁷Fe]-meso-tetraphenylporphyrin, and these are discussed in relation to the effect of the axial ligand on the iron–porphyrin binding profiles.

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DOI: https://doi.org/10.1039/C39780000106
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1978, 106-107

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¹⁵ N nuclear magnetic resonance studies of iron(II) low spin complexes of ¹⁵N and ⁵⁷Fe labelled porphyrin

I. Morishima, T. Inubushi and M. Sato, J. Chem. Soc., Chem. Commun., 1978, 106 DOI: 10.1039/C39780000106

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Journal of the Chemical Society, Chemical Communications