Acetates of sterically hindered secondary alcohols and of tertiary alcohols are reduced by lithium in ethylamine to afford predominantly the corresponding alkanes, rather than the parent alcohols.
R. B. Boar, L. Joukhadar, J. F. McGhie, S. C. Misra, A. G. M. Barrett, D. H. R. Barton and P. A. Prokopiou, J. Chem. Soc., Chem. Commun., 1978, 68 DOI: 10.1039/C39780000068
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