The c.d. spectra for 5-alkyl-5-(3-hydroxy-1-methylbutyl)barbituric acids (2) in trifluoroethanol show two Cotton effects in the 230–260 nm region opposite in sign from those of similar compounds lacking a side-chain 3-hydroxygroup.
F. I. Carroll, D. Smith, G. N. Mitchell and A. Sobti, J. Chem. Soc., Perkin Trans. 2, 1977, 983 DOI: 10.1039/P29770000983
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