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A detailed study of the fluorescence and phosphorescence characteristics of morphine, diamorphine (heroin), and a number of morphine derivatives has been undertaken. Fluorescence decay times have been determined where appropriate by using a time-correlated single photon counting technique. The effect on intersystem crossing rate of a heavy atom substituent in the chromophore has been investigated.
A. Bowd and J. H. Turnbull, J. Chem. Soc., Perkin Trans. 2, 1977, 121 DOI: 10.1039/P29770000121
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