Base-catalysed cis-trans equilibria for dimethyl, diethyl, and methyl ethyl cyclopentane-1,3-dicarboxylates were established at several temperatures and solvents. Thermodynamic parameters were calculated thereof and conformational analytical implications are discussed, using a new approach for assessing entropy effects.
B. Fuchs and P. S. Wechsler, J. Chem. Soc., Perkin Trans. 2, 1977, 75 DOI: 10.1039/P29770000075
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