Issue 23, 1977
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Microbiological transformations of 3α-acetoxy-17a-aza-D-homo-5α-androstan-17-one and of 3α-acetoxy-5α-androstan-17-one with the fungus Cunninghamella elegans

Trevor A. Crabb,   John A. Saul  and  Roger O. Williams  

Abstract

3α-Acetoxy-17a-aza-D-homo-5α-androstan-17-one is hydroxylated by Cunninghamella elegans to 3α-acetoxy-6β-hydroxy-, 3α-acetoxy-7α-hydroxy-, 3α,11α-dihydroxy-, and 3α,11β-dihydroxy-17a-aza-D-homo-5α-androstan-17-one, in contrast to the near carbocyclic analogue, 3α-acetoxy-5α-androstan-17-one, which is hydroxylated to 3α-acetoxy-6β,11β-dihydroxy-5α-androstan-17-one, 1β,3α-dihydroxy-5α-androstan-17-one, and 3α-acetoxy-6β-hydroxy-5α-androstane-11,17-dione.

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Article information

DOI
https://doi.org/10.1039/P19770002599
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1977, 2599-2603

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Microbiological transformations of 3α-acetoxy-17a-aza-D-homo-5α-androstan-17-one and of 3α-acetoxy-5α-androstan-17-one with the fungus Cunninghamella elegans

T. A. Crabb, J. A. Saul and R. O. Williams, J. Chem. Soc., Perkin Trans. 1, 1977, 2599 DOI: 10.1039/P19770002599

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