Iodine triacetate has been prepared from iodine trichloride and silver acetate. Its reactions with cyclohexene, 5α-androst-2-ene, and methyl cinnamate in acetic acid are stereo- and regio-specific, leading to vicinal trans-iodo-acetates and trans-iodohydrins. The reactions of iodine trichloride with cyclohexene and 5α-androst-2-ene, and of iodine pentaoxide with cyclohexene have also been examined.
R. C. Cambie, D. Chambers, P. S. Rutledge and P. D. Woodgate, J. Chem. Soc., Perkin Trans. 1, 1977, 2231 DOI: 10.1039/P19770002231
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