The use of chiral diols each containing a two-fold axis of symmetry to achieve asymmetric reductions of some ketones with metal hydrides is described. The symmetry of these complexes simplifies interpretation of the observed enantioselectivity.
N. Baggett and P. Stribblehill, J. Chem. Soc., Perkin Trans. 1, 1977, 1123 DOI: 10.1039/P19770001123
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