SCHEDULED MAINTENANCE
Esters are formed from carboxylic acids and alkyl iodides upon treatment with t-butyl hypochlorite and iodine in carbon tetrachloride. Evidence is presented for a heterolytic mechanism whereby the iodine in the alkyl halide is replaced by the acyloxy-group of the acyl hypoiodite in the presence of iodine monochloride.
M. R. Britten-Kelly, A. Goosen, J. Lovelock and A. Scheffer, J. Chem. Soc., Perkin Trans. 1, 1977, 945 DOI: 10.1039/P19770000945
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