Caldariellaquinone {6-(3,7,11,15,19,23-hexamethyltetracosyl)-5-methylthiobenzo[b]thiophen-4,7-quinone (7)} has been isolated from cultures of Caldariella acidophila, an extremely thermophilic and acidophilic bacterium. The structure was determined by degradation, spectroscopic, and 13C biosynthetic studies.
M. De Rosa, S. De Rosa, A. Gambacorta, L. Minale, R. H. Thomson and R. D. Worthington, J. Chem. Soc., Perkin Trans. 1, 1977, 653 DOI: 10.1039/P19770000653
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