Issue 0, 1977

Capillary phenomena. Part 5.—Equilibrium and stability of solid cones in fluid/fluid interfaces

Abstract

Conditions are given for the equilibrium paths followed by cones (axis vertical) in interfaces between two fluids, when raised and lowered by an applied force: using a tensiometer or a rigid (damped) device. Circumstances are described under which these conditions are stable. The instability and detachment of cones with contact angle θ < χ+ 90°, where χ is the half-angle at the apex of the cone generating triangle, at a maximum in the displacement of the cone apex gives a method of determining the fluid/fluid interfacial tension. Conditions under which cones can float unaided are also given. Comparison is made with the behaviour of other capillary systems.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1977,73, 1882-1890

Capillary phenomena. Part 5.—Equilibrium and stability of solid cones in fluid/fluid interfaces

E. A. Boucher and H. J. Kent, J. Chem. Soc., Faraday Trans. 1, 1977, 73, 1882 DOI: 10.1039/F19777301882

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