Issue 0, 1977
From the journal:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

Oxidation of 1-phenylethanol in the presence of cobalt acetylacetonates

Gábor Vasvári  and  Dezsö Gál  

Abstract

The oxidation of 1-phenylethanol has been investigated in the presence of Co(acac)2 and Co(acac)3. It is established that in the presence of Co(acac)2 the oxidation is preceded by the formation of a Co(acac)2—ROH complex and the fast oxidation stops abruptly due to the deactivation of the catalyst. The rate constants and the overall activation energy were determined. In the presence of Co(acac)3 the oxidation began after an induction period. It is assumed that the actual catalyst for this process is Co(acac)2. The overall activation energy has been determined.

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Article information

DOI
https://doi.org/10.1039/F19777301537
Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1977,73, 1537-1543

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Oxidation of 1-phenylethanol in the presence of cobalt acetylacetonates

G. Vasvári and D. Gál, J. Chem. Soc., Faraday Trans. 1, 1977, 73, 1537 DOI: 10.1039/F19777301537

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