The 14N hyperfine coupling constant in di-t-butyl nitroxide dissolved in ethanol + carbon tetrachloride mixtures depends on the solvent composition. The analysis of the effect in terms of hydrogen-bonding between the radical and ethanol, and self-association of the latter, is discussed. Coupling constants for the radical in seven simple alkanols are reported.
N. M. Atherton, M. R. Manterfield, B. Oral and F. Zorlu, J. Chem. Soc., Faraday Trans. 1, 1977, 73, 430 DOI: 10.1039/F19777300430
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